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Tier Harribel is an Arrancar and the 3rd Espada in Sōsuke Aizen's army. Her aspect of death is Sacrifice.
Harribel is a calm fighter and has a strong personality. She witness the battle that took place in Las Noches between Ichigo Kurosaki and fellow Espada Grimmjow Jaegerjaquez and remarked on how much it resembled a battle between two Espada. Harribel along with her Fracción (Apache, Mila-Rose and Sun-Sun) are part of the group of Arrancar that Sōsuke Aizen brings to invade Karakura Town, but when the rest of the Gotei 13 appear to hinder their efforts she engages in battle with Tōshirō Hitsugaya and his Visored allies.
Main article: Tier Harribel
"It could be that our friends and family will just see us as deranged murderers and carry on believing that we're the ones in the wrong. However, whether it will fix this or whether it won't, in order to get Tsukishima out of their lives killing him is the only option we have left! Can you do it? Do you have the resolve to take his life even with no guarantee things will change?" - Kūgo Ginjō asks Ichigo Kurosaki if he can kill Shūkurō Tsukishima, chapter 454.
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