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Rangiku Matsumoto is a Shinigami, the Lieutenant of the 10th Division of the Gotei 13, serving under Captain Tōshirō Hitsugaya.

Despite coming across as lazy and fun-loving, she is a skilled fighter and intuitive when it comes to helping out her friends. Rangiku plays an important role during the Ryoka Invasion, protecting an unconscious Momo Hinamori from being attacked by her childhood friend, Gin Ichimaru, and later discovering the bodies of the Central 46 alongside her captain. She later appears in the Human World with a task force to help to fight the Arrancar Invasion. During the attack on the Fake Karakura Town by Sōsuke Aizen's forces, she takes on three Arrancar at once. While initially gaining the upper hand and receiving assistance from Hinamori, Rangiku is brutally incapacitated by Ayon and taken off the battlefield until several hours later, where she attempts to stop Gin from going through with his plan for Aizen.

Main article: Rangiku Matsumoto